Year in Review: 2018 Top Posts Collection

Happy New Year in 2019! We are very happy with your company and encouragement that push us to insist on updating every week. On the occasion of the arrival of 2019, let us summarize the Top Posts in 2018 for you.

Metal History

“Metal History” is a popular column we have opened this year, aiming at introducing the discovery of different kinds of metals. Among them, the Top 3 posts in this column are as follows:

How was titanium discovered? | History of Titanium

Titanium is a metal element that is known as “space metal” because of its light weight, high strength and good corrosion resistance. The most common compound of titanium is titanium dioxide, and other compounds include titanium tetrachloride and titanium trichloride. Click the title of the article to know more.

Discovery and development of tungsten | History of Tungsten

The history of tungsten dates back to the 17th century. At that time, miners in the Erzgebirge Mountains of Saxony, Germany, noticed that some of the ore would interfere with the reduction of cassiterite and produce slag. The miners gave the mines some German nicknames: “wolfert” and “wolfrahm”. Click the title of the article to know more.

How was cerium discovered? | History of Cerium

Cerium is the most abundant rare earth elements. It is a silvery gray active metal, whose powder is easily oxidized in the air and soluble in acid. Cerium has been widely used in the automotive industry as a catalyst to reduce emission, and in glass industry as glass polishing materials. Cerium sputtering target is an important material in optical coating. Click the title of the article to know more. Click the title of the article to know more.

Metal Materials Application

Apart from history, we also introduce the multiple applications of these metal materials. Among them, the Top 3 posts in this column are as follows:

Molybdenum Target Mammography Detection

At present, molybdenum target mammography is considered the recommended breast screening examinations for women’s breast cancer, one of the major causes of deaths among women, affects about 12% of women around the world. Click the title of the article to know more.

Application of titanium and titanium alloys in medical field

Titanium is an ideal medical metal material and can be used as an implant for the human body. Titanium alloy has been widely used in the medical field and has become the material of choice for medical products. Click the title of the article to know more.

A short analysis of sputtering targets for semiconductor application

Semiconductors have high requirements for the quality and purity of the sputtering materials, which explains why the price of anelva targets is relatively high. Click the title of the article to know more.

Sputtering Targets

Sputtering Target is the consistent keyword of our website, and thus we have shared many useful information about some specific type of sputtering targets. Our intention is to help you better understand these materials—their properties, applications, developing prospect and so on. And the followings are the posts you really have to read. Among them, the Top 3 posts in this column are as follows:

PVD vs. CVD: What’s the difference?

In recent years, physical vapor deposition (PVD) and chemical vapor deposition (PVD) have wide applications in various industries to increase the hardness of tools and molds or apply beautiful colors to the products. Thus these two methods are considered as the most attractive surface coating technologies. Click the title of the article to know more.

What is the Indium Bonding for Sputtering Target?

The term “indium bonding” in thin film coating industry, simply speaking, refers to bond two (or more) sputtering targets with indium (In), or one (or more) with indium plate together. Click the title of the article to know more.

What is Target Poisoning in Sputtering Deposition?

At some stage in the sputtering deposition, positive ions are continuously amassed on the surface of the sputtering target. Due to the fact that those fantastic ions aren’t neutralized, the negative bias of the target surface gradually decreases, and progressively the normal operation can not be completed. This is the target poisoning phenomenon. Click the title of the article to know more.

Glad you are part of SAM’s 2018. Next year, please continue following us and we promise to give you more valuable information! Also, you can visit our official website https://www.sputtertargets.net/ for more information.

Happy New Year to All

Introduction to Physical Vapor Deposition Technologies

Thin Film Deposition

Thin film deposition technology refers to the preparation of thin films on the surface of materials used in the fields of machinery, electronics, semiconductors, optics, aviation, transportation and etc., in order to impart certain properties (such as heat resistance, wear resistance, corrosion resistance, decoration, etc.) to these materials.

The two most common forms of thin film deposition techniques are physical vapor deposition (PVD) and chemical vapor deposition (PVD).

Physical Vapor Deposition —PVD

PVD is a process that achieves the transformation of the atoms from the source materials to the substrate to deposit a film by physical mechanisms such as thermal evaporation or sputtering.

PVD includes evaporation, sputtering and ion plating.

Evaporation

Evaporation is a common method of thin-film deposition. It is also called vacuum evaporation because the source material is evaporated in a vacuum. The vacuum allows the vapored particles to travel directly to the substrate, where they condense and deposit to form a thin film.

Evaporation (PVD)
Evaporation (PVD)

Sputtering

Sputtering is a physical vapor deposition (PVD) method of thin film deposition. It is a process whereby particles are ejected from a solid target material (sputtering target) due to the bombardment of the target by energetic particles.

Sputtering (PVD)
Sputtering (PVD)

Ion Plating

Ion plating is a physical vapor deposition (PVD) process which uses a concurrent or periodic bombardment of the substrate, and deposits film by atomic-sized energetic particles.

Ion Plating (PVD)
Ion Plating (PVD)

Characteristics of the main physical vapor deposition method

SAM Sputter Target Evaporation Sputtering Ion Plating
Particle energy eV 0.1-1 1-10 0.1-1
Deposition Rate um/min 0.1-70 0.01-50 0.1-50
Adhesion Poor Good Very Good
Density Low High Very High

Among the above three methods, although Ion plating’s film adhesion and density are better, due to technical limitations, the other two methods (evaporation and sputtering) are currently more widely used. In general, sputtering is the best PVD technology.

Stanford Advanced Materials (SAM) is one of the most specialized sputtering targets manufacturers, please visit https://www.sputtertargets.net/ for more information.

Copper Sulfide Sputtering Targets Are The Best Sputtering Materials

Sputtering is a thin film deposition process in the modern technology world of CDs, semiconductors, disk drives and optical devices industries. Sputtering is the process at an atomic level, where the atoms are automatically sputtered out from the sputtering materials and then be deposited on another substrate, such as a solar panel, semiconductor wafer or optical device. It is an effect of the severe bombard of the high energy particles on the target.

In general, sputtering occurs only when kinetic energy is said to be bombarding particles at very high speeds, which is much higher than a normal thermal energy. At the atomic level, this makes thin film deposition more precise and accurate than that by melting the source material using conventional thermal energy.

Copper Sulfide is the best material for Sputtering Targets. It can be molded into the shape of Plates, Discs, Step Targets, Column Targets and Custom-made. Copper Sulfide is a combination of two materials—Copper and Sulphur. The chemical name of the product is CuS, which offers you the Copper Sulfide product with more than 99 percent purity.

 

CopperCyprus is the original source material for the chemical element Copper. The people of Middle East initially discovered it in 9000 BC. “Cu” is the canonical chemical symbol of copper.

 

SulfurWhereas Sulfur, otherwise known as sulphur, is first introduced in 2000 BC and discovered by Chinese and Indians. It is a chemical name originated from the Sanskrit word ‘sulvere’, and the Latin ‘sulfurium’. Both names are for sulfur.

 

Copper Sulfide metal discs and plates are highly adhesive and resistant against oxidation and corrosion. Using Copper Sulfide sputtering targets to deposit thin films will not produce highly reflective and extremely conductive films, but can also extensively increase the efficiency of the source energy.

So to achieve the desired noticeable result in a sputtering deposition, the built-up process used to fabricate the Sputtering Targets should be critical. A Copper Sulfide targeted material will give the best result. However, material like only an element, alloys, mixture of elements, or perhaps a compound can be used for the purposes.

For more information about sputtering targets, please visit http://www.sputtertargets.net/.

What is the Indium Bonding for Sputtering Target?

The term “indium bonding” in thin film coating industry, simply speaking, refers to bond two (or more) sputtering targets with indium (In), or one (or more) with indium plate together.

Indium

Indium can be uniquely used in lower temperature solders, is one of the softest materials. Indium is preferred for target bonding because of its excellent thermal conductivity of all available bonds. In addition, indium is the most efficient material at drawing heat away from the sputtering target. Most materials can be indium bonded and there are just a few exceptions.

Apart from indium bonding, indium is also popular for a variety of uses and purposes, such as creating alloys, photoconductors, and thermistors.

Indium bond

Sputtering target can be cracked, warped or damaged due to inadequate cooling, low hardness or other reasons. From this point of view, although target bonding does generate a fee, it can well protect your target from damage. It is especially true for those less-strong target materials and precious metal materials.

Elastomer is an alternative bonding method that touts a higher temperature capability over the indium bond. Elastomer bonds are recommended when you are consistently melting indium bonds. We also recommend elastomer bonding for low melting point target materials, as well as, temperature sensitive compounds and targets that have either low density or are especially fragile.

indium target bonding

Indium bonding is preferred in applications where:

Cryogenic stability is needed

Sealing requires high levels of hermeticity

Maximum thermal transfer is required

Bonding to not-metallic surfaces

Flux cannot be used

Backing plates

OFHC Copper Backing Plate is another well-known backing plate. It is frequently used to bond ceramic targets because of its non-magnetism and low coefficient of thermal expansion. This metal has good electrical and thermal characteristics while also being easy to machine, easy to soften, and readily available at a low cost. Copper backing plates can be re-used, with care, 20 or more times.

Molybdenum plate is usually used to substitute copper plate if copper is not appropriate in the application. For instance, the coefficient of expansion for copper is mismatched with some ceramics. And for high-temperature bonding, copper may also oxidize badly or warp. In these conditions, molybdenum is a more suitable material.

SAM Sputter Target

If you are looking for an indium bonding manufacturer, SAM is undoubtedly your best choice. Stanford Advanced Materials is devoted to machining standard backing plates and working together with the Taiwan Bonding Company for providing bonding services. For questions about target bonding materials, methods and services, please see our listing of frequently asked questions (FAQs).

Related blog: When do you need target bonding?

When do you need target bonding?

This post gives an answer when should require a target bonding service and how to choose different bonding services.

SAM®Sputtering targets are the material that is indispensable during a sputtering process. Sputtering targets are normally comprised of one to three distinct parts, including the backing tube, a bonding layer, and the target material. The figure shown below is an example of rotatory sputtering target. Among them, the former two parts are not unnecessary, depending on the type of materials required for the sputtering process and the manufacturing techniques that are available to produce the target. If the target material is brittle and can be easily broken during the sputtering process, it is necessary to require a target bonding service.

parts of rotatory target
parts of rotatory target

 

In terms of the target material, sputtering target varies from pure metal to ceramics. Many pure metal targets are stronger, thus some of them can be made into single piece or monolithic targets without the backing tube or a bonding layer. In contrast, ceramic targets usually require the three-layer construction technique because they are not strong enough to support their own weight and the pressure inside the tube.

Ceramic targets are usually bonded to a stainless steel backing tube because of its non-magnetism and low coefficient of thermal expansion. The thermal expansion coefficients of the backing tube material and the target can never be ignored, because a great difference between these two coefficients can lead to large stress concentrations in the target material during the sputtering process that can cause the ceramic materials to crack and break off.

In addition to stainless steel backing, indium bonding is used more frequently due to its low melting point, good thermal conductivity, low chemical reactivity, and good adhesion to most materials. Indium has the best thermal conductivity of all available bonds and is the most efficient at drawing heat away from the target. Most materials can be indium bonded but there are a few exceptions, mainly due to the low melting point of indium. Indium has a melting point of 156.6°C so temperatures in excess of 150°C will cause the bond to melt and fail.

Stanford Advanced Materials is devoted to machining standard backing plate. Please visit https://www.sputtertargets.net/ for more information.

Optical Coating: Anti-wear films (hard coating film)

As a raw material for the deposition of hard coatings by PVD technology, the target will directly affect the physical and mechanical properties of the hard coating films. Therefore, the selection of good sputtering targets for coating preparation is of great practical significance.

Spectacle lenses made of inorganic materials or organic materials can cause scratches on the surface of the lens due to friction with dust or gravel (silicon oxide) during daily use. Compared with glass sheets, organic materials have lower hardness and are more likely to cause scratches. Through the microscope, we can observe that the scratches on the surface of the lens are mainly divided into two types: one is because the scratches generated by the gravel are shallow and small, and the wearer is not easy to detect; the other is the scratch caused by the larger gravel, which is deep and peripherally rough, and will affect people’s vision if it is in the central area. In order to improve the anti-wear of optical lenses, people began to study optical coatings to produce anti-wear films.

glass-lens-scratches-optical-coating

Technical Development

First generation anti-wear film technology

Anti-wear films began in the early 1970s when it was thought that glass lenses were not easy to wear because of their high hardness, while organic lenses were easy to wear because they are too soft. Therefore, the quartz material is plated on the surface of the organic lens under vacuum to form a very hard anti-wear film. However, due to the mismatch between the thermal expansion coefficient and the substrate-based material, the film is easy to take off and the film layer is brittle, thus the anti-wear effect is not ideal.

Second generation anti-wear film technology

After the 1980s, researchers theoretically found that the mechanism of wear is not only related to hardness, but also related to the dual characteristics of “hardness/deformation” of the film material, that is, some materials have higher hardness but less deformation, while some materials have lower hardness but greater deformation. The second generation of anti-wear film technology is to apply a high hardness and less brittle material to the surface of the organic lens by the immersion process.

Third generation anti-wear film technology

The third generation of anti-wear film technology was developed after the 1990s, mainly to solve the problem of wear resistance after the organic lens is coated with anti-reflection film. Since the hardness of the organic lens substrate and the hardness of the anti-reflection film layer are very different, the new theory suggests that an anti-wear film layer is required between the two layers, so that the lens are not easy to be scratched. The hardness of the third-generation anti-wear film material is between the hardness of the anti-reflection film and the lens base, and the friction coefficient is low and is not easily cracked.

optical coating

Hard coating film preparation technology

Physical vapor deposition is the mainstream technology of hard coating materials preparation. The main methods are sputtering, such as magnetron sputtering; and cathode arc evaporation, such as multi-arc ion plating.

Sputter Coating

Sputtering uses ions generated by an ion source (generally Ar ions), and accelerates them into a high-speed. The high-energy ion beam in a vacuum electric field bombards the surface of the sputtering target, and kinetic energy exchange between ions and target atoms. When the ion energy is sufficient, atoms on the surface of the sputtering target will leave the target and deposit on the surface of the substrate to form a thin film.

Cathodic arc evaporation

Cathodic arc evaporation is a PVD deposition method that uses arc evaporation electrode material as a deposition source. The low-voltage, high-current electron beam forms an arc on the surface of the material. When the arc moves on the surface of the target, the high current forms a local high temperature, which causes the surface of the metal ion evaporation material on the target surface to form a plasma. After that, a high-speed high-energy ion current is obtained by the electric field, and a film of the coating material is deposited on the surface of the substrate.

As a raw material for the deposition of hard coatings by PVD technology, the target will directly affect the physical and mechanical properties of the hard coating films. Therefore, the selection of good sputtering targets for coating preparation is of great practical significance.

Please visit https://www.sputtertargets.net/ for more information.

A short analysis of sputtering targets for semiconductor application

Semiconductors have high requirements for the quality and purity of the sputtering materials, which explains why the price of anelva  targets is relatively high.

Undoubtedly, sputtering targets are the most important raw materials in current semiconductor manufacturing processes. Their quality and purity play a key role in the subsequent production quality of the semiconductor industry chain. And anelva targets refer to those sputtering targets used in the semiconductor industry.

Application requirements

Semiconductors have high requirements for the quality and purity of the sputtering materials, which explains why the price of anelva  targets is relatively high. In the semiconductor manufacturing process, if the impurity content of the sputtering target is too high, the formed film cannot achieve the required electrical properties, and it is liable to cause short circuit or damage of the circuit, which will seriously affect the performance of the film.

Therefore, when purchasing semiconductor targets, be sure to find a reliable sputtering targets manufacturers for high-quality & high-purity sputtering targets.

blue computer circuit board closeup , semiconductor industry

Market Size

With the rapid development of terminal applications such as consumer electronics, the market sales of high-purity sputtering targets are expanding.

According to statistics, in 2015, the global high-purity sputtering target market sales reached 9.48 billion US dollars, of which, the semiconductor sputtering target market sales of 1.14 billion US dollars. It is estimated that in the next five years, the market size of the world’s sputtering targets will exceed 16 billion US dollars, and the CAGR (Compound Annual Growth rate) of the high-purity sputtering target market will reach 13%.

According to statistics from WSTS (World Semiconductor Trade Statistics), the global target market is expected to grow at the same rate as 2017 (13%). In 2016, the global sputtering target market capacity was US$11.36 billion, an increase of 20% compared to US$9.48 billion in 2015. It can be inferred that the market size of the global high-purity sputtering target in 2018 is about 14.5 billion US dollars.

Stanford Advanced Materials (SAM) Corporation is a global supplier of sputtering targets such as metals, alloys, oxides and ceramic materials, which are widely used in multiple industries. Please visit https://www.sputtertargets.net/ for more information.

What is Target Poisoning in Sputtering Deposition?

At some stage in the sputtering deposition, positive ions are continuously amassed on the surface of the sputtering target. Due to the fact that those fantastic ions aren’t neutralized, the negative bias of the target surface gradually decreases, and progressively the normal operation can not be completed. This is the target poisoning phenomenon.

The word “poisoning” is normally used to describe the poisoning as a result of the consumption of positive toxic substances via dwelling organisms. However, have you ever heard of target poisoning? Do you already know what it is?

Definition

Despite the fact that the same word is used for “poisoning”, the meaning of target poisoning and human poisoning is completely different. At some stage in the sputtering deposition, positive ions are continuously amassed on the surface of the sputtering target. Due to the fact that those fantastic ions aren’t neutralized, the negative bias of the target surface gradually decreases, and progressively the normal operation can not be completed. This is the target poisoning phenomenon.

target poisoning
target poisoning

Reasons

Target poisoning does not always occur. It is associated with various reasons, of which the following factors are the most significant:

1 There is air leak or water leakage occurs in the vacuum chamber; There are volatile components in the vacuum chamber; The vacuum chamber is not filled with argon, but mixed with air or other gases.

2 The impurity component reacts with the sputtering material to form certain substances, which cover the surface of the sputtering target and affect the film formation speed.

3 There is a change in secondary electron emission, which results in a change of the discharge impedance. Consequently, at the same discharge power, the current and voltage can change substantially as reactive gas is introduced.

Solutions

Luckily, as I mentioned before, the poisoning the the target surface does not always occur, and it can be prevented by the following methods:

1 Ensure that the vacuum chamber is not leaking; Clean the inside of the vacuum chamber regularly to remove volatile components.

2 Irradiate the sputtering target with a medium source or Radio Frequancy (RF) source for one to two hours.

3 If target poisoning occurs, the sputtering target should be removed and be polished with sandpaper.

Please visit https://www.sputtertargets.net/ for more information.

Basic Requirements of High Quality Titanium Sputtering Target

Purity

Purity is one of the main performance indicators of sputtering targets because it has a great influence on the performance of the film. Taking titanium target as an example, the higher the purity is, the better the corrosion resistance and electrical and optical properties of the sputtered film are. However, in practical applications, the purity requirements of the sputtering targets are not the same. Generally, the purity requirements of industrial targets are not high, but the sputter targets for semiconductors, display devices have very strict requirements–the purity requirements of magnetic film targets are generally 99.9% or more, and the purity of indium oxide and tin oxide in ITO targets is required to be not less than 99.99%.

Continue reading “Basic Requirements of High Quality Titanium Sputtering Target”

Semiconductor industry: The importance of Anelva target

The sputtering target materials can be divided into metal target (pure metal gold, aluminumtitanium, etc.), alloy target (aluminum-scandium alloy, cobalt-aluminum alloy, aluminum-titanium alloy, etc.) and ceramic compound target (oxides, nitride, silicides, etc.) according to their different chemical compositions; when it comes to different application fields, it can be categorized into semiconductor target, planar display target, solar cell target, and other target materials. Anelva target refers to the sputtering target used in semiconductor industry.

Although the proportion of Anelva target is just about 3% among all the sputtering targets, it cannot be denied that its application in semiconductor chip market is important and irreplaceable. There are generally two kinds of Anelva target: wafer materials and packaging materials. Today we mainly focus on wafer manufacturing materials because they have relatively high technical barriers than the other.

The inner part of the semiconductor is composed of tens of thousands of meters of metal wiring, and the sputtering target material is the key consumption material for making these wiring. In other words, the Anelva target is the core of semiconductor wafer manufacturing. Since the chip is elaborate, it has high requirements for sputtering target material used in the manufacturing process. Generally, the purity of the target material is over 99.999%.

Semiconductor wafers are the basic material for manufacturing chips (as shown below). It is small but complicated. The production of wafer mainly involves 7 kinds of semiconductor materials and chemicals. The most important raw material for semiconductor integrated circuits is silicon, which is widely found in rocks and gravel in the form of silicate or silicon dioxide in nature. The manufacturing process of silicon wafers can be divided into three basic steps: silicon purification, monocrystalline silicon growth, and wafer formation. Apart from silicon, the manufacturing process of 200mm (8-inch) and below wafers is usually mainly made of aluminum, and the manufacture of 300mm (12-inch) wafer mostly uses advanced copper interconnection technology.

Semiconductor wafer

In conclusion, with more extensive use of semiconductor chips, the demand for aluminum, titanium, tantalum and copper, the four mainstream Anelva target, will also increase. There is currently no alternative to these target materials, either technically or economically, so, as I mentioned before,  they are important and irreplaceable.

Please visit https://www.sputtertargets.net/ for more information.